Forecasting the levels of chemical elements content in soils of different genesis for the assessment of their eco-energy status
Abstract
Grounded the new elaborated method for predicting of trace elements (TE) and heavy metals (HM) content in the soils of different genesis, which was elaborated by analysis the indicators parameters of their organic matter and energy characteristics in different natural-climatic zones of Ukraine, also of contaminated and intensive fertilizer soils. The method aims for the assessment of soils ecological-energy state due to the installation of the new natural relations of indicators humus, energy and elemental status of soils of different types, as a result, expanding the range of diagnostic indicators with identifing their paired combinations and simultaneously increasing of informativeness, accuracy, express testing of chemical elements (TE, HM) predicting levels, energy and humus state of soils to predict and ecological regulation of their quality. The essence of the elaborated utility model – by the identify of new patterns of soil properties indicators and receive four matching pairs of humus (CGA/CFA, Ctotal), elemental and energy state (calorific value of humus, the reserves of energy in the soil layer of 0–20 cm) as soil indicators with the using of mathematical-statistical analysis of the obtained regression equations for the accurate determination is predicted the TE and HM content in soils of different types of background conditions, with the distribution algorithm of the method for different soil types in certain climate zones in the conditions of technogenic pollution and technological load, risk and the presence of man-made pollution to make timely management decisions. Elaborated method ensures the rapidity of the assessment and improves the accuracy of the TE/HM status prediction, energy and humus state of soils of different genesis with the identification of soils ecological differences to predict their quality by assessment of ecological functions for the ranking of energy intensity indicators of the soil. The method is applicable in the environmental regulation of TE and HM content, regulation of the loads (technogenic, technological) on a soil system, agroecology to address issues of biological agriculture, bio-energy and energy of soil formation; monitoring the quality of humus and the status TE and the dangers of excess accumulation of HM, in the soil humus indicators and /or energy state; efficient environmental management of soils, both in background conditions and with different anthropogenic impacts and in the research practice. Grounded the method was examined on the of soils simples in different natural-climatic zones of Ukraine, contaminated soils in Kharkiv, Donetsk and Lugansk regions, and intensive fertilizer (organo-mineral, organic and mineral system of fertilizers) of soils in Kiev, Kharkiv, Poltava and Lviv region.
References
A.c. 1481681 A1 SU, 1989. Sposob prognozirovaniya vosproizvodstva pochvennogo plodorodiya [Author's certificate 1481681 A1 SU. МPК: G01N 33/24 The method for predicting the reproduction of soil fertility] V. M. Volodin, A. Ye. Phedorchenko, L. I. Birukova, R. F. Eremina. 4194328/30-15; appl. 12.02.1987; publ. 23.05.1989, Bull. 19. 5 р. (in Russian).
Dobryva ta yikh vykorystannia, 2010. [The Handbook: Fertilizers and their using]. Aristey. Kyiv (in Ukrainian).
Fateev, A. I., Samokhvalova, V. L., 2012. Diahnostyka stanu khimichnykh elementiv systemy hrunt-roslyna [The diagnosis of the chemical elements of the soil-plant system]. KP «Urban Typography», Kharkiv (in Ukrainian) URL: http://www.issar.com.ua/uk/vydannya/ diagnostyka-stanu-himichnyh-elementiv-systemy-grunt-roslyna.
Glazovskaya, M. A., 1997. Metodologicheskie osnovy ocenki ekologo-geohimicheskoj ustojchivosti pochv k tekhnogennym vozdejstviyam [The methodological framework for the assessment of ecological and geochemical soil resistance to anthropogenic influences]. MGU Moscow (in Russian).
Izrael, Y. A., 2001. Sostoyanie i kompleksnyj monitoring prirodnoj sredy i klimata. Predely izmenenij [Status and State and integrated monitoring of environment and climate. The limits of changes]. Nauka, Moscow (in Russian).
Kovda, V. A., 1973. Osnovy uchenija o pochvah. Obshhaja teorija pochvoobrazovatel'nogo processa [Fundamentals of soils. The general theory of soil-forming process]. Nauka, Moscow. Vol. 1 (in Russian).
Kovda, V. A., 1974. Biosfera, pochvy i ih ispolzovanie [The biosphere, soil, and their use. Materials of the 10 Intern. Congress of Soil Science]. Nauka, Moscow (in Russian).
Lal, R., 2007. Anthropogenic influences on world soils and implications to global food security. Advances in Agronomy 93, 69–93.
Lobell, D. B., Burke, M. B., Tebaldi, C., Mastrandrea, M. D., Falcon, W. P., Naylor, R. L., 2008. Prioritizing climate change adaptation needs for food security in 2030. Science 319, 607–610.
Lopushniak, V., 2012. Energetichnij potencіal gumusu temno-sіrogo pіdzolistogo gruntu zapapdnogo lіsostepu Ukrainy [Energetic capacity of humus dark-grey podzolic soil in the Western Forest-steppe of Ukraine]. Announcer of the Sumy national agrarian university. Series "Agronomics and biology" 9(24), 57–59 (in Ukrainian).
Lopushniak, V., 2014. Vpliv sistem dobriv na vmіst gumusu v temno-sіromu opіdzolenomu ґruntі Zahіdnogo lіsostepu [Influence of fertilizer systems on the humus content in dark grey podzolized soil of Western Forest-steppe] Vіsnik agrarnih nauk 2, 5–9 (in Ukrainian).
Lopushniak, V. I., 2012. Dinamіka frakcіjno-gruppovogo skladu gumusu temno-sіrogo pіdzolistogo gruntu za rіznih sistem udobrennya. [Dynamics fractionally-group composition of humus dark gray podzolic soils under various fertilization systems]. Zemlerobstvo ta tvarinnictvo peredgіrnih ta gіrnih rajonіv 54(2), 58–64 (in Ukrainian).
Lopushniak, V. I., 2013. Ahrokhimichni ta ahroekolohichni osnovy system udobrennia silskohospodarskykh kultur u Zakhidnomu Lisostepu Ukrainy [Agrochemical bases and agro-environmental fertilization of crops in Western steppes of Ukraine]. Dissertation of doctor of Agricultural Sciences: 06.01.04 – agrochemistry. Kharkiv (in Ukrainian).
Lopushniak, V. I., 2013. Ekologіchnij stan temno-sіrogo pіdzolistogo ґruntu pri rіznih sistemah udobrennya [Ecological state dark gray podzolic soil under different fertilization systems]. Agroekological journal 3, 47–52 (in Ukrainian).
Lopushniak, V. I., 2015. Fertilization system as a factor of transforming the soil humus state. Agricultural Science and Practice 2, 39–44.
Medvedev, V. V., 2012. Monitoring pochv Ukrainy. Itogi. Zadachi. [Monitoring of Ukraine soils. Results. Tasks]. "Urban typography", Kharkov (in Russian).
Medvedev, V. V., Plisko, I. V., 2003. Prognozirovanie izmeneniya bonitetov pochv v Ukraine [Forecasting of soils bonitet changes in Ukraine]. Gruntoznavstvo 4(1–2), 11–18 (in Russian).
Orlov, D. S., 1999. Pochvennye ful'vokisloty: istorija ih izuchenija, znachenie i real'nost' [Soil fulvic history of their study, the meaning and reality]. Eurasian Soil Science 9, 1165–1171 (in Russian).
Orlov, D. S., Birjukova, O. N., Rozanova, M. S., 2004. Dopolnitel'nye pokazateli gumusnogo sostojanija pochv i ih geneticheskih gorizontov [Additional indicators of soils humus status and their genetic horizons]. Eurasian Soil Science 8, 918–926 (in Russian).
Orlov, D. S., Grishina, L. A., 1981. Praktikum po himii gumusa [Practice on humus chemistry]. MGU, Moscow (in Russian).
Orlov, D. S., Sadovnikova, L. K., Lozanovskaya, I. N., 2002. Ekologiya i ohrana biosfery pri himicheskom zagryaznenii [Ecology and protection of the biosphere in chemical pollution]. Higher school, Moscow (in Russian).
Orlov, O. L., 2002. Enerhoiemnist yak kryterii humusovoho stanu gruntiv [Energy intensity as a criterion of soil humus]. Bulletin of Lviv NU named after I. Franko. Biology Series 31, 111–115 (in Ukrainian).
Pat. na korysnu model 105444 UA, 2016. Sposib prognozuvannya elementnogo statusu sistemi grunt – roslina dlya ekologichnogo normuvannya ta upravlinnya yakistyu u trofichnih lantsyugah [Pat. for useful model 105444 UA, МПК (2016.01): A01B 79/00, G01N 33/24 (2006.01) The method for predicting the trace element status of the soil – plant system for environmental regulation and quality management in food chains / V. L. Samokhvalova, V. I. Lopushnjak,
A. I. Fateev, et. al, u201507444; appl. 24.07.2015; publ. 25.03.2016, Bull. 6. 8 р.] (in Ukrainian). URL:http://base.uipv.org/searchINV/search.php?action=viewdetails&IdClaim=221436&chapter=description
Pat. na korysnu model 107854 UA, 2016. Sposib prognozuvannya rivniv vmistu mikroelementiv i vazhkih metaliv gruntiv riznogo genezisu dlya otsinyuvannya yih ekologichnih ta produktsiynih funktsiy [Pat. for useful model 107854 UA, МПК: G01N 33/24 (2006.01) The method for predicting of trace elements and heavy metals the levels in soils of different genesis for the assessment of their environmental and productive functions / V. L. Samokhvalova, Ye. V. Skrylnyk, L. O. Shedey, V. I. Lopushnjak et.al. u201512399; appl. 15.12.2015; publ. 24.06.2016, Bull. 12. 8 р.] (in Ukrainian). URL:http://base.uipv.org/searchINV/search.php?action=viewdetails&IdClaim=224643&chapter=description
Pat. na korysnu model 58720 UA, 2011. Sposib prohnozuvannia zmin vmistu rukhomykh form tsynku i midi u zroshuvanomu temno-kashtanovomu grunti pry systematychnomu vnesenni mineralnykh dobryv [Pat. for useful model 58720 UA, МPК (2011.01): A01B 79/00. Method of predicting changes in the content of mobile forms of zinc and copper in irrigated dark chesnut soils at regular fertilization / A. V. Melashych, I. D. Filipiev, R. A. Vozhehova, et al.; U201010994; appl. 13.09.2010; publ. 26.04.2011, Bull. 8. 3 p.] (in Ukrainian).
Pat. na korysnu model 89939 UA, 2014. Sposib prohnozuvannia zabezpechenosti gruntiv mikroelementamy [Pat. for useful model 89939 UA, МPК (2014.01): A01B 79/00 The Method for predicting soil micronutrients availability / A. I. Fateev, D. O. Semenov, K. B. Smirnova, et al.; № u201311847; appl. 08.10.2013; publ. 05.12.2014, Bull. 9. 5 р.] (in Ukrainian).
Pat. na korysnu model 95649 UA, 2014. Sposib prohnozuvannia vmistu rukhomykh form vazhkykh metaliv ta mikroelementiv u gruntovii systemi dlia efektyvnosti remediatsii i vykorystannia [Pat. for useful model 95649 UA, МPК (2014.01): A01B 79/00, A01N 63/00, B09C 1/00, C09K 17/00, G01N 33/24 (2006.01) The method for predicting the heavy metals and trace elements mobile forms content in soil system for efficiency remediation and using / V. L. Samokhvalova, V. I. Lopushnjak, A. I. Fateev, V. M. Gorjakina, u201408753; appl. 04.08.2014; publ. 25.12.2014, Bull. 24. 7 р.] (in Ukrainian). URL:http://base.uipv.org/searchINV/search.php?action=viewdetails&IdClaim=207936&chapter=description
Pat. Ukrayini na vinahid UA, 2016. Sposib prognozuvannya vmistu tsinku u gruntah riznogo genezisu dlya otsinyuvannya yih ekologo-energetichnogo stanu [Pat. of Ukraine for invention UA, МПК: G01N 33/24 (2006.01), application u201512847 (UA). The method for predicting the content of zinc in soils of different genesis for the assessment of their eco-energy status / V. L. Samokhvalova, Ye. V. Skrylnyk, L. O. Shedey, V. I. Lopushnjak et.al. appl. 25.12.2015; publ. 25.12.2016, Bull. 21. 12 р.] (in Ukrainian).
Patent Ukrajiny na vynaxid № 83563 UA, 2008 Sposib prohnozuvannja ekolohichnoho stanu hruntu v zonax texnohennoho zabrudnennja [Pat. of Ukraine for invention 83563 UA, МPК (2006): A01B 79/02 (2006.01), C09K 17/00, G01N 33/24 (2006.01) The method for predicting the ecological condition of the soil in the zones of technogenic pollution / V. L. Samokhvalova, A. I. Fateev; а200611387; appl. 30.10.2006; publ. 25.07.2008, Bull. 14. 6 р.] (in Ukrainian). URL: http://base.uipv.org/searchINV/search.php?action=viewdetails&IdClaim=121760&chapter=description
Revich, B.A., 2007. «Goryachie tochki» himicheskogo zagryazneniya okruzhayushchej sredy i zdorov'e naseleniya Rossii ["Hot spots" of the chemical pollution of the environment and the health of the Russia's population]. Acropolis, the Public Chamber of the RF, Moscow (in Russian).
Samokhvalova, V. L., Fateev, A. I., 2006. Vplyv tekhnohennoho polielementnoho zabrudnennia vazhkymy metalamy na orhanichnu rechovynu gruntu [The influence of technogenic polyelemental heavy metal pollution on soil organic matter]. Sci. Bulletin of Chernivtsi NU. Series Biology 293, 152–163 (in Ukrainian).
Samokhvalova, V. L., Fateev, A. I., Luchnykova, Е. V., 2011. Ekoloho-heokhimichna otsinka fonovoho rivnia vmistu riznykh form mikroelementiv gruntu [Ecological and geochemical assessment of background levels of trace elements various forms in soils]. Bulletin of Lviv NU named after I. Franko. Biology Series 55, 125–133 (in Ukrainian). URL:http://prima.franko.lviv.ua/faculty/biologh/wis/wis.htm
Samokhvalova, V. L., Lopushnyak, V. I., Fateev, A. I., Gorjakina, V. M., Shymel, V. V., 2015. Prognozuvannya mikroelementnogo statusu gruntovoyi sistemi dlya efektivnoyi remediatsiyi ta vikoristannya [Prediction of elemental status of soil systems for effective remediation and using]. Agricultural Chemistry and Soil Science 84, 55–63 (in Ukrainian). URL: http://nbuv.gov.ua/ UJRN/agrohimigrn_2015_84_9
Samokhvalova, V. L., Lopushnyak, V. I., Fateev, A. I., Samokhvalova, P. А., Mandryka, O. V., Shymel, V. V., 2015. Prognozirovanie elementnogo statusa sistemy pochva – rastenie Prognozirovanie elementnogo statusa sistemy pochva – rastenie [Prediction of the trace element status of the soil – plant system]. Ecological Bulletin 4(34), 5–14 (in Russian). URL: http://www.iseu.bsu.by/wp-content/uploads/2016/01/E%60V-34.pdf
Shedey, L. O., 2010. Rozrobyty systemu operatyvnoi informatsii shchodo stanu gruntiv v ekolohichno chystykh ahrozonakh ta opratsiuvaty zakhody z polipshennia yikh produtsiinykh i ekolohichnykh funktsii [Elaborating the operational information system of the soil status in ecological clean agrozones and work out measures to improve their ecological functions and the productivity]. Scientific report № 0106U004783 on research 01.02.02-031 NSC «ISSAR named after O.N. Sokolovsky», Guiding by M. M. Miroshnichenko; Kharkiv. 88 p.] № 0106U004783 (in Ukrainian).
Shedey, L. O., Shevchenko, N. G., 2006. Enerhopotentsial chornozemu opidzolenoho za tradytsiinoi, orhanichnoi i resursozberihaiuchoi system zemlerobstva [Energy intensity of chernozem podzolic for traditional, organic and resource-efficient farming systems]. Spec. issue to the VII Congress of the Ukrainian Society of soil scientists and agrochemists. Kharkiv: NSC «ISSAR named after O. N. Sokolovsky». Book 3, 161–163 (in Ukrainian).
Skrylnyk, E. V., 2008. Vmist, sklad, enerhoiemnist humusu ta yikh zmina [The content, composition, humus energy and their changes]. Bulletin of Agricultural Science of Southern region of Ukraine 9, 36–40 (in Ukrainian).
Skrylnyk, E. V., 2010. Transformatsiia humusovoho stanu gruntiv ta yikh enerhoiemnosti pid vplyvom riznykh system udobrennia [The transformation of soils humus status and their energy intensity due to the various fertilization systems]. Bulletin TSNZ APV Kharkiv region 7, 184–194 (in Ukrainian).
Smirnov, P. M., Muravin, E. A., 1981. Agrohimija [Agrochemistry]. Kolos. Moscow (in Russian).
Tarariko, Y. O., Nesmashna, O. Y., 2000. Enerhetychna kharakterystyka osnovnykh typiv gruntiv Ukrainy zalezhno vid sposobiv yikh vykorystannia [Energy characteristics of the main types of soil in Ukraine depending on their uses]. Journal of Agricultural Sciences 4, 18–22 (in Ukrainian).
Tarariko, Y. O., Nesmashna, O. Y., Lychuk, H. I., 2007. Otsinka ta rehuliuvannia enerhoiemnosti gruntiv [Assessment and regulation of soils energy intensity. Ukrainian fitotsenology collection]. 25, 41–47 (in Ukrainian).
Vlasiuk, P. A., Dmytrenko, P. O., 1962. Dovidnyk ahronoma po udobrenniu [Handbook of agronomist on the fertilizer]. Derzhsilhospvydav, Kiev (in Ukrainian).
Volobuev, V. R., 1974. Vvedenie v jenergetiku pochvoobrazovanija [Introduction to the energetics of soil]. Nauka, Moscow (in Russian).
Volobuev, V. R., 1982. Otcenka produktivnosti agrocenozov s ispol'zovaniem jenergeticheskih kriteriev [Evaluation of agrocenosis productivity using energy criterions]. Eurasian Soil Science 7, 83–88 (in Russian).
Volobuev, V. R., 1983. Agrojenergetika – aktual'naja nauchnaja i prakticheskaja problema [Agroenergetics is an actual scientific and practical problem]. Eurasian Soil Science 6, 83–89 (in Russian).
Zholudeva, I. D., Kovalev, V. P., Yehorenkova, V. A., 2010. Vyznachyty bioenerhetychni kharakterystyky gruntiv Stepovoi i Lisostepovoi zon Ukrainy dlia rozrobky ahrotekhnolohii vidtvorennia humusu i optymizatsii enerhetychnoho ta ekolohichnoho stanu gruntiv [Identify the bioenergetic soil characteristics of Steppe and Forest-steppe zones of Ukraine to elaboration of agricultural technologies of humus restoration and energy for optimization of soil environmental and energy status [Text]: Scientific report № 0106U002945 on research 01.03.02 – 043 NSC «ISSAR named after O. N. Sokolovsky», Kharkiv. 45 p.]; Inv. № 0104V00368. (in Ukrainian).
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